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Home / Industries / Bulk Chemical Loading / Ammonium HydroxideAmmonium Hydroxide (NH4OH) Handling Design, Loading & Installation
Increase Safety & Maximize Productivity with Innovative Loading Solutions
What is ammonium hydroxide?
Ammonium hydroxide, also called aqueous ammonia, ammonia solution, or ammonia water is a solution of ammonia gas in water. Ammonia hydroxide is a colorless aqueous solution with a pungent aroma. Typically used as a cleaning agent in common industrial and household cleaners, ammonium hydroxide is also used in the manufacture of products such as rayon, fertilizer, rubber, and plastic. Corrosive to aluminum alloys, copper, copper alloys, and galvanized surfaces. aqueous ammonia is specified at concentrations of 19%, 25%, or 29% pure ammonia. Commercial grade anhydrous ammonia, however, is 99.5 to 99.7% pure, with a minimum of 0.3% water content.
In the United States, ammonium hydroxide is a “tight-fill” (closed-loop) loading operation and is loaded and unloaded into rail cars via chemical hoses or 3” stainless steel loading arms. If not handled properly ammonium hydroxide can cause serious injuries and personal protective equipment (PPE) is required. Additionally, because operators are on top of the vehicles during the loading process, high-quality fall prevention systems are essential to ensure operator safety while increasing throughput.
Ammonium hydroxide is typically shipped in 26,000 gallon DOT-111 insulated or non-insulated tank cars with safety valves. The rails cars themselves are ~ 9′ outside diameter with an overall length of ~45’ to 50′, with a 6’ x 6’ center opening or off-set crash box openings.
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View Full TextCustomize Your Project
In order to create a custom loading solution for your facility, we will need to know the following information:
- The railcar connection locations require flexibility. Do you know what the breadbasket connections look like?
- Are you using liquid and vapor arms/hoses as two separate devices or a piggyback arm?
- Is the loading station indoors or outdoors?
- Is the loading area temperature controlled?
- How will you spot your railcars?
Our highly trained technical sales team will conduct a detailed site survey to determine the specifications of your project including dimensions, obstructions, and access issues. Our goal is to provide the safest working environment possible protecting operators and the equipment at your facility while helping you improve throughput and productivity.
Your Project Needs
Whether you are looking for a turn-key installation, on-site supervision, or a safety maintenance program, we are ready to assist you with as little or as much as you need. Our project management and supervision teams are the best in the business at supporting the needs of your company.
- Collaborative Design – Our loading platform specialists will work with you one-on-one to design the best loading solution for your facility.
- Contract Review – Our team of experts will review all drawings and associated documents relating to the contract prior to site arrival.
- Risk Assessment – A thorough site risk assessment will be conducted.
- Shipment Inspection – We will inspect your order for detection of any shipping damage or abnormalities.
- Material Receiving – Supervised off-loading and transport are available on-site as needed.
- Installation Management – Our experienced team will supervise and coordinate installations as needed.
- Start-up & Commissioning – On-site training is available as needed for users and maintenance personnel.
Loading Arms
In most cases, we recommend rigid pipe loading arms wherever possible. The benefits of loading arms include:
- balance throughout their movement envelope
- designed not to hit the ground, protecting the asset and the operator
- ergonomic – one-person operation
- fitted with manual or actuated valves
- fitted with optional purge/vent facilities
- can be moved into position with ease and left hanging in the air while the operator prepares the tanker connection
- parked neatly
Alternatively, hoses are not recommended because they:
- require an annual pressure test
- are difficult to stow neatly when not in use
- can be dropped & driven over
- are very heavy to use if fitted with a valve at the tanker connection point
- cannot be easily heated or have vent/purge valves fitted to them
- are prone to catastrophic failure
Tank truck loading and unloading procedures are similar to railcar applications with the trailers meeting established DOT requirements for transporting ammonium hydroxide or other similar commodities. Approved DOT trailers include MC 307 or low pressure chemical ISO containers. Trailers and ISOs are typically bottom unloaded. An extension pipe with two valves is flanged to the top of the trailer.
All trailers must be equipped with pressure relief valves and trailers with bottom outlets must be equipped with remote controlled stop valves.
Ammonium Hydroxide Loading Platform
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Below are some of the loading and unloading solutions for illustrative purposes only. Our experts will work with you and your team for a custom solution to suit your needs.
Ammonium Hydroxide Loading
Ammonium hydroxide is typically loaded into railcars or tank trucks via boom-supported stainless steel loading arms or chemical hoses with a flange connection. The arm or hose has a top inlet with a control valve to ensure that it is self-draining after use and is supported by a by-pass arm along the length of a mechanical loading arm to improve handling. One liquid and one vapor arm can be installed, or alternatively, both the liquid and vapor hoses can be mounted on one by-pass arm. When unloading, a rigid stainless steel self-draining loading arm with PTFE, Fluorocarbon, Chemraz, or Viton seals can be utilized. Purge lines can be fitted to the arm, for nitrogen purging. Additional features such as parking latches with proximity sensors can be incorporated into the total system to ensure the arm is correctly stowed when not in use before any rail movement can occur.
Loading Gangways and Safety Cages
A 36″-48″ wide access gangway is preferable as it helps improve access and egress to and from the vessel. A wide gangway reduces the risk of the operator’s PPE getting caught, torn or damaged, and will improve productivity and safety. Powered gangways are also an option, with both hydraulic and pneumatic solutions being commonly used. Each gangway is fitted with a two-rail safety cage for the railcar crash box. This will be a centered 6’x6’ safety cage to sit directly over the crash box. This will provide a safe, secure work environment for operators while connected to their breathing apparatus.
SafeRack’s GX SAS gangways use Retractalok power-assist technology allowing operators to raise or lower effortlessly, light as a feather to lift, and solid as a rock. Tested in the most critical applications, this revolutionary new gangway outperforms all others. Available in multiple lengths and widths.
Learn MoreMAXRack Elevating Safety Cage
As an alternative to our two and four-rail safety cages, some customers prefer our MAXRack elevating safety cages. The ultimate fall prevention solution engineered to keep operators safe and productive. Designed for both trucks or railcars, and available in multiple cage lengths and widths. Safe, durable, and easy to use. MAXRack is built rock-solid with galvanized steel column supports and lifting arms (cages can be Aluminum, Galvanized, or Stainless Steel depending on application) Available in two power options – Pneumatic Air Drive and Electric Drive (Explosion and Non-Explosion Proof).
Learn MoreAmmonium Hydroxide Eye Wash/Drench Showers
ANSI guidelines state that eyewash/drench showers need to be located 10 seconds or 55’ (16.8m) from contaminants or hazardous materials. Eyewash stations need to be on the same horizontal plane with no obstructions.
Installation of our standard combination Drench Shower/Eyewash Unit saves limited space and fits easily into any work environment.
Ammonium Hydroxide Spill Containment
Spill containment pans are provided at the point of loading operations and are an essential component in the overall site safety and environmental protection of your operation. Ammonium Hydroxide Grounding
Ammonium hydroxide is not generally combustible. However, the risk of fire and explosion exists upon contact with heavy metals and their salts forming explosive compounds. Industry best practice includes the grounding of all vessels before starting the loading or unloading process. - Ground controllers — ensure true grounding before product flow is permitted
- Explosion-proof enclosures — meet or exceed UL, CSA, and Ex requirements
- Non-sparking tools are also recommended while working around this product
Ammonium Hydroxide Safety Gates
Safety Gates will be installed at the top of stairs and any other openings to ensure operator safety at all times. YellowGate Safety Gates
Our industrial safety gates are the most flexible product on the market with the ability span openings between 16” and 36” and are field adjustable using nothing more than a wrench. Learn More
Ammonium Hydroxide Options
- Lighting – Lighting both over and under the platform will be provided. For overcast days or second shifts, proper lighting is essential for improved safety and improved productivity.
- Platform & Canopies – Full platform canopies reduce exposure to the elements and improve safety and productivity for loading operations.
- Operator Shelter – Depending on your site requirements, an operator or guard building on the loading platform might be considered. This can be customized to meet specific site requirements.
- Wheel Chocks – Railcar wheel chocks provide fast blocking of all types of railcars and meet OSHA regulations to safely prevent railroad cars from moving during loading or unloading operations. This is a requirement by the Department of Homeland Security.
Personal Protective Equipment PPE Requirements
Eye/Face Protection: Wear chemical safety goggles. A face shield (with safety goggles) may also be necessary. Skin Protection: Wear chemical protective clothing including gloves, aprons, and boots. Coveralls or long sleeve shirts and pants may be necessary for some operations. Wear a chemical protective, full-body encapsulating suit, and self-contained breathing apparatus (SCBA). Suitable materials include butyl rubber, neoprene rubber, Viton®, Viton®/butyl rubber, Barrier® – PE/PA/PE, Silver Shield® – PE/EVAL/PE, Trellchem® HPS, Trellchem® VPS, Saranex®™, Tychem® BR/LV, Tychem® Responder® CSM, Tychem® TK. The following materials should NOT be used: natural rubber, polyvinyl chloride. Recommendations are NOT valid for very thin neoprene rubber gloves (0.3 mm or less).
Respiratory Protection: Up to 5 ppm:
(APF = 10) Any chemical cartridge respirator with cartridge(s) providing protection against chlorine*; or Any supplied-air respirator*.
*Reported to cause eye irritation or damage; may require eye protection.
APF = Assigned Protection Factor
Recommendations apply only to National Institute for Occupational Safety and Health (NIOSH) approved respirators. Refer to the NIOSH pocket guide to chemical hazards for more information.
Use a local exhaust ventilation and enclosure, if necessary, to control the amount in the air. Consider using a corrosion-resistant exhaust ventilation system separate from other ventilation systems. It may be necessary to use stringent control measures such as process enclosure to prevent product release into the workplace. Use backup controls (e.g. double mechanical pump seals) to prevent the release of this material due to equipment failure. * For illustrative purposes only. Our experts will work with you and your team for a custom solution to suit your needs Customer Reviews
4 5I was not just a number. I felt like I was number one.SafeRack stood behind their product. Working to make sure I received the correct parts. The first person I talked with did not know what my equipment was, “BUT” instead of passing the buck, they found someone who did know and worked with all parties to get the part needed. Great team work. Not everyone knows it all but the great ones know how to find the right people to get the job done. I was very impressed. Best thing I can say is “follow through.” I was not just a number. I felt like I was number one. This does not happen very much anymore. Most places have forgotten the customer is number one. You still have it. Keep up the good work.
By James Caban from BASF Corp. on 7/9/145 5My sales rep was Johnny on the spot.Product was delivered quicker than I thought it would get here. I was looking at possibly 6 to 7 weeks. We received it in about 3 weeks. My sales rep was Johnny on the spot. He gave me a couple of follow up calls that helped a lot. We have used SafeRack for some time, and will continue to use SafeRack. The products are better quality, last longer, and for me personally, they look better. I have recommended them to our other terminals, and most have switched over.
By Mike Glaze from Buzzi Unicem on 7/7/165 5We needed an Aluminum Self-Adjusting StairI really liked the responsiveness of the sales team and short lead time. You have a very good product.
By from Siemer Milling Company on 3/16/204 5I have dealt with a competitor and did not receive the same level of service after the sale.As usual, very responsive. Service was great and delivery was on time. I like talking to Dana Brogdon, she is very personable and exudes the feeling SafeRack is there for Nustar. The gangways meet our safety requirements, they are reliable and easy to operate. I have dealt with a competitor and did not receive the same level of service after the sale.
By Jerry Hilgendorf from Nustar Logistics, LP on 6/11/135 5Maui Replacement PartsSafeRack provided friendly service and our product was delivered on time.
By Sean Bent from Delta Terminal Services, INC. on 5/30/204 5One of the best, if not the best, salesmen that I have ever dealt with.Pat Early was absolutely one of the best, if not the best, salesmen that I have ever dealt with. He was always responsive to my needs, understood the changes and assisted in getting them taken care of. I have recommended SafeRack to all the other plants within my division of Owens Corning. Scott Hite was another outstanding salesman that I had the pleasure of dealing with. Our original design called for an auto-tarping system (which is how I found out about SafeRack), but after investigating it with Scott and Pat, they came to me and informed that due to building specs you were unable to install one. That is where a couple of competitors kind of stopped, but Pat kept bringing up other possible solutions. His dedication to the project is why we ended up choosing SafeRack. When the units came, they were just as described. They were packaged secure and together, and were a simple unload. Install went without issue, because of the way that SafeRack loaded the parts and pieces. The end user (the truck drivers) like the ease of use of the gangways. The Owens Corning Rockford Plant is grateful to SafeRack for assisting us in reducing a safety risk at a fair price.
By Harley White from Owens Corning Sales, LLC on 1/7/13Ammonium Hydroxide 101
Things to know about Ammonium Hydroxide
Ammonium hydroxide is regulated by the U.S. Department of Transportation (DOT) and is classified as a corrosive hazardous material with the DOT identification number UN 2672.
Ammonium hydroxide is a colorless liquid solution with a pungent odor. Concentrations up to a nominal 29% solutions are available commercially. Effective use of ammonium hydroxide is the neutralization of acids.
Only properly trained and equipped personnel should be permitted to load or unload ammonium hydroxide tank cars and tank trucks. Operators should wear approved PPE equipment including impervious clothing, footwear, gloves, and a respirator.
Ammonium hydroxide is dangerous to human health, and as a corrosive chemical, acute exposure can cause severe skin burns and eye damage. Do not breathe fumes/mist/vapors as they can be fatal if inhaled. Use only outdoors, or in a well-ventilated area.
First-aid measures for exposure include:
- Removing operators from the source of exposure and into the fresh air.
- Remove contaminated clothing immediately
- Wash skin thoroughly with soap and water
- Flush eyes with tepid water for 15 minutes.
- If ingested do not induce vomiting, but immediately call your local poison control center.
Aspiration into the lungs can cause fatal chemical pneumonitis. If ingestion has occurred, assume there is a risk of aspiration into the lungs.
When heated, ammonium hydroxide will give off ammonia vapor, which is a strong irritant to the eyes, skin, and respiratory tract. When handled properly outdoors, it’s not generally a fire hazard. However, indoors and in confined areas, ammonia vapors may become a fire hazard, especially if oil or other combustible materials are present.
Ammonium hydroxide is corrosive to most metals including bronze, brass, carbon and milled steel, so great care should be taken to avoid contact with these materials. However, aluminum and stainless steel have little to no effect when exposed to this solution.
Is your plant or facility compliant with ANSI, OSHA, and local safety codes? We can help!
EMERGENCY EYEWASHES / SHOWER EQUIPMENT AND THE ANSI/ISEA Z358.1 – 2014 STANDARD
Following eye contact, you must start washing with water immediately to prevent permanent damage. In the event of skin contact, you must start washing with water immediately to prevent slow-healing chemical burns.
Are you aware that ANSI guidelines state that Eye Wash/Drench Showers need to be located 10 seconds or 55′ from contaminates or hazardous materials and located on the same horizontal plane, with no obstructions? If bottom loading/unloading, an additional shower should be located at grade as well. SafeRack provides the above equipment plus much more needed to keep employees safe and expedite bulk chemical loading and unloading.
OSHA Regulation Experts – Does your existing chemical safety equipment or chemical loading systems meet OSHA’s latest requirements? SafeRack’s professional technical sales consultants are available to meet with your team to make recommendations to keep your facility in front of OSHA’s ever-changing country and region-specific standards and regulations, including lifeline and trolley beam fall arrest systems, metal stairs, and access platforms.
Why SafeRack?
The SafeRack approach is a collaborative one. Let’s call it The SafeRack Way. We have, over many years amassed a great deal of experience and understanding of the safety aspects involved in loading road tankers and railcars, as well as the behavioral habits of the operators.
Experts In Chemical Loading
- Acetic Acid
- Acetic Anhydride
- Acetonitrile
- Acrolein
- Acrylic Acid
- Acrylonitrile
- Aluminum Chloride
- Aluminum Sulfate
- Ammonia
- Ammonium Hydroxide
- Ammonium Nitrate
- Aniline
- Benzene
- Benzyl Chloride
- Bromotrifluoromethane
- Butadiene
- Carbon Dioxide
- Caustic
- Chlorine
- Chloroform
- Chlorosulfonic Acid
- DEF (Diesel Exhaust Fluid)
- Diethylene Glycol
- Dimethylformamide
- Dodecylbenzene Sulfonic Acid
- Ethanol
- Ethyl Acetate
- Ethyl Chloride
- Ethylene
- Ethylene Dichloride
- Ethylene Glycol
- Ethylene Oxide
- Ferric Chloride
- Ferrous Chloride
- Hexane
- Hydrochloric Acid
- Hydrofluoric Acid
- Hydrofluorosilicic Acid
- Hydrogen Cyanide
- Hydrogen Peroxide
- Hydrofluoric Acid
- Hypochlorous Acid
- Isopropyl Acetate
- Liquid Argon
- Liquid Nitrogen
- Liquid Oxygen
- Maleic Anhydride
- MDI
- Methanol
- Methyl Chloride
- Methyl Ethyl Ketone
- Methyl Methacrylate
- Methyl Isocyanate
- Molten Sulphur
- Nitric Acid
- Oleum
- Phenol
- Phosphoric Acid
- Phosphorus Oxychloride
- Phosphorus Trichloride
- Polypropylene
- Renewable Diesel
- Sodium Cyanide
- Sodium Hydroxide
- Sodium Hypochlorite
- Styrene Monomer
- Sulfuric Acid
- Sulfur Dioxide
- Titanium Tetrachloride
- Toluene
- Toluene Diisocyanate
- Turpenitne
- UAN (Urea Ammonium Nitrate)
- UREA
- Vinyl Acetate
- Vinyl Chloride
- Xylene
- Zinc Chloride
- Agro-Chemical
- Specialty Chemical
- Petrochemical
North America’s largest loading terminal
World-leading designer, manufacturer, and installer of truck and railcar loading platforms
As one of the primary railcar loading points, Hardisty is one of the major crude oil hubs in North America and a major origination point of pipelines that export to the United States. SCS was asked to supply and construct a SafeRack crude oil loadout terminal spanning nearly half a mile. The USD Hardisty terminal can load up to two 120-railcar unit trains per day and consists of a fixed loading rack with 62 railcar loading positions enclosed, separate control, operator, and mechanical buildings, as well as a unit train staging area and loop tracks capable of holding multiple unit trains simultaneously. SCS also supplied and installed boom-supported loading arms with supply and vapor management systems.
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